http://www.holmanchemistry.net/uploads/8/2/2/9/8229266/cryptophanes_comprehensivesupramolchemii_2024.pdf WebCrystalline M 3 L 2 complexes with either single cage or triply interlocking [2]catenane chiral structures are formed the self-assembly of host-like ligands with transition metals. This article is part of the themed collection: Supramolecular Chemistry.
Cryptophanes - Holman Research Group
WebApr 21, 2011 · Several dynamic hexaimine cryptophanes, that are built up from two triformylcyclotribenzylene cavitands and three diamino linkers and spontaneously assemble in water in the presence of a suitable templating guest, are reported. X-ray structure, kinetics and thermodynamics of assembly and molecular recognition properties are discussed. WebMar 29, 2024 · Homochiral metallo-cages with tris-chelate metal coordination are known both from achiral 13a, 13b and resolved chiral ligands. 13c – 13e Metallo-cages that show homochiral self-sorting from a racemic mixture of ligand enantiomers observed in solution are rare, 14 although these include Pd II metallo-cryptophanes. 8a The simultaneous … immortals fenix rising map
M3L2 metallo-cryptophanes: [2]catenane and simple cages
WebCryptophane sensors designed for proteins, metal ions, nucleic acids, pH, and temperature have achieved nanomolar-to-femtomolar limits of detection via a combination of129Xe hyperpolarization and chemical exchange saturation transfer (CEST) techniques. WebMar 31, 2024 · Cryptophanes and hemicryptophanes are host molecules, built from the cyclotriveratrylene (CTV) unit, and are presently widely explored due to the development … WebDec 31, 2013 · Cryptophanes are organic molecular receptors known for their complexation properties toward neutral and cationic species in organic or aqueous media. Small halogenomethanes and alkanes,... immortals fenix rising review